I have just tried out DoubleTwist, and it is great !
It synchronizes my iTunes content to my Motorola Milestone (a.k.a. Droid) including converting file formats to something readble on the Android.
Basically it is an application that runs on your PC. It reads your iTunes configuration. Then, when you plug in your Android, it lets you pick which iTunes playlists you want synchronized to the device.
The DoubleTwist application includes an option for picking Podcasts to synchronize to the device, including Video podcasts.
I had tried DoubleTwist out a month ago, but I discarded it because it did not work with iTunes if the music was located on mapped File shares. But now it works with mapped drives. So, DoubleTwist stays installed.